Barcelona star striker Robert Lewandowski and defender Gerrard Pique were shown red cards by the referee.
In other marquee fixtures, Juventus will square off against FC Nantes while Roma will face RB Salzburg.
Pique had his moments on the field as he stayed on for 83 minutes.
Lionel Messi is currently experiencing a great season at Paris Saint-Germain with 11 goals and 12 assists in 16 matches across all competitions.
Barcelona faced their second consecutive UCL elimination after they lost 3-0 against Bayern Munich on Wednesday.
The UCL match between Barcelona vs Bayern Munich will take place on Thursday, October 27 at 12:30 am IST at the Camp Nou.
DIS filed a complaint in 2015 over the irregularities in Neymar's transfer to the Spanish side.
The La Liga match between Real Madrid and Barcelona will take place on Sunday, October 16 at 7:45 pm IST at the Santiago Bernabeu.
Robert Lewandowski scored a brace to help the Catalan giants settle with a 3-3 draw against Inter Milan.
In group A fixtures, Italian club Napoli beat Dutch giants Ajax 4-2 to continue their winning streak.
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